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Diagrammaticillustration(a)andclinicalphotograph(b)showingthecreationofanenvelopeflaptoexpose the roots Fig. However, if the equation is modified by the insertion of the Brown sþ values instead of the Hammett s values (because a positive charge develops during the transition state), more satis- factory correlations can be made, even for electron-donating groups (see Table 9.

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